HYDROGEN SULFIDE (H2S)
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1 Dc N: Revisin Date: Revisin N. 0 Initial Versin Preparatin: Safety Mgr Authrity: President Issuing Dept: Safety Page: Page 1 f 6 Purpse The purpse f this prgram is t establish minimum requirements fr site specific safety, which will enhance safety in the ccupatinal setting where hydrgen sulfide is present r is recgnized as being ptentially present. Scpe This prgram sets frth accepted practices fr Hydrgen Sulfide (). This prgram applies t all emplyees f, temprary emplyees, and any cntractrs wrking fr RICHARD L. OREAIR & COMPANY. When wrk is perfrmed n a nn-wned r perated site, the peratr s prgram shall take precedence, hwever, this dcument cvers emplyees and cntractrs and shall be used n wned premises, r when an peratr s prgram desn t exist r is less stringent. Definitins Cntingency Plan - a site-specific written dcument that prvides an rganized plan fr alerting and prtecting the public within an area f expsure fllwing the accidental release f all ptentially hazardus atmspheric cncentratins f hydrgen sulfide. Expsure Level - permissible expsure level f hydrgen sulfide is 10 PPM fr an 8-hur, time weighted average. Gas Detectr Instrument - An instrument/detectr t measure levels f. Instruments may be electrnically r manually perated. Hydrgen Sulfide () - is an extremely deadly, txic gas that in its pure state is clrless and is heavier than air. Additinally: It is the secnd mst txic gas knwn t man, ranking behind hydrgen cyanide and ahead f carbn mnxide. It has the dr f rtten eggs at lw cncentratins. In higher cncentratins rapidly paralyze the lfactry nerves (sense f smell). Is sluble in water and is flammable and pses a definite threat f explsin. Parts Per Millin (PPM) - parts f vapr r gas per millin parts f cntaminated air by vlume. Persnal Mnitr - An electrnic instrument wrn n the persn that is set t alarm at 10 PPM f. Pssible Lcatins f Where May Be Expsed t During Their Jb Functins While clients are required t ntify f knwn lcatins the majrity f time can be lcated in drilling peratins, recycled drilling mud, blwuts, water frm sur crude wells, blwuts, tank gauging (tanks at prducing, pipeline and refining peratins), during rutine field maintenance invlving hydrcarbns, tank batteries and wells. Venting - the prcess f discharging a material t the atmsphere thrugh a series piping and/r venting devices, t facilitate the prper and safe dispersin f txic materials and t minimize persnnel expsure. Uncntrlled cpy if printed. Valid n day f printing nly. Printed n: 14 December 2016
2 Dc N: Revisin Date: Revisin N. 0 Initial Versin Preparatin: Safety Mgr Authrity: President Issuing Dept: Safety Page: Page 2 f 6 Key Respnsibilities Managers and Supervisrs Shall ensure all emplyees wh are t be assigned t wrk at lcatins where hydrgen sulfide is knwn t be present, r suspected t be present in any cncentratin, have been trained in hydrgen sulfide safety. T ensure emplyees have been medically apprved t wear respiratrs and trained n the safe use f respiratrs, including a respiratr fit test in accrdance with s Respiratry Prtectin Prgram. T ensure emplyees have been trained and familiar with persnal mnitrs and gas detectin instruments. T have been prvided with the client's safety prcedures. T ensure the necessary respiratry equipment t perfrm the wrk safely is available. That each emplyee has been prvided with a cpy f this prgram. Emplyees Prcedure Emplyees are respnsible t cmply with this prgram. Characteristics f Hydrgen Sulfide The characteristics f hydrgen sulfide include: being txic, clrless, with the dr r rtten eggs at lw cncentratins, is sluble in water and is flammable: Txicity See table belw. Hydrgen sulfide is a very dangerus and deadly gas - it is clrless and heavier than air. It can accumulate in lw places and in small cncentratins. Expsure t certain cncentratins f can cause serius injury r death. Clr - is clrless yu can t see it. Odr it has a strng, pungent, smewhat distasteful dr similar t rtten eggs. In higher cncentratins, it can deaden the sense f smell (lfactry nerve). D Nt Rely On Smell T Detect H2s Rely Strictly On Instruments Designed T Measure Cncentratins Of. Slubility mixes with water. Flammability is an explsive gas. Txic By Prducts presence can create sulfur dixide which can ignite withut warning Txic Effects f Hydrgen Sulfide CONCENTRATION PHYSICAL EFFECT.01 PPM Can smell dr. 10 PPM Obvius and unpleasant dr. Beginning eye irritatin. ANSI permissible expsure level fr 8 hurs (enfrced by OSHA). 100 PPM Immediately Dangerus t life r Health (IDLH) Kills smell in 3-15 minutes; may sting eyes and thrat. May cause cughing and drwsiness. Pssible Uncntrlled cpy if printed. Valid n day f printing nly. Printed n: 14 December 2016
3 Dc N: Revisin Date: Revisin N. 0 Initial Versin Preparatin: Safety Mgr Authrity: President Issuing Dept: Safety Page: Page 3 f PPM 500 PPM 700 PPM delayed death within 48 hurs. Kills smell shrtly, stings eyes and thrat. Respiratry irritatin. Death after 1-2 hurs expsure. Dizziness; breathing ceases in a few minutes. Need prmpt rescue breathing (CPR). Self-rescue impssible because f lss f muscle cntrl. Uncnscius quickly; death will result if nt rescued prmptly PPM Uncnscius at nce, fllwed by death within minutes. Health Effect f Expsure t Hydrgen Sulfide Sme basic health effects f H2s can include eye irritatins, effects nerve centers f the brain which cntrl breathing. General Requirements shuld have a written cnfined space prgram per 29 CFR and emplyees must be aware f site specific cntingency/emergency plans and wners cntingency plan prvisins. Each persn entering a designated lcatin, regardless f the cncentratin, shall wear a persnal mnitr that is set t alarm at 10 PPM and shall carry a 5-minute escape pack with them at all times. When the alarms sund the emplyees must either evacuate the area r dn the SCBA's r airline respiratrs. Emplyees must evacuate the area, dn SCBA's r airline respiratrs upn sunding f alarm. When wrk requires pening any equipment n lcatin that has the ptential f releasing cncentratins f at 100 PPM r higher, tw r mre trained persns shall be present and fllw these prcedures prir t and during the pening f the equipment: Each persn entering the lcatin shall dn a persnal mnitr prir t entry. A tailgate meeting will be held with everyne n lcatin t discuss the wrk plan, the respnsibilities f each persn and the site specific cntingency plan. Each persn shall have either a self-cntained breathing apparatus (SCBA) r a supplied airline respiratr equipped with a 5-minute escape pack, and shall be wrn when pening the equipment t the surrunding atmsphere. At least ne persn (per tw wrkers), equipped with a SCBA will act as a stand-by persn and may nt participate in the wrk being perfrmed until the atmsphere has been tested and fund t have n present in quantities ver 10 PPM. The stand-by persn shall be statined up wind, within 100 feet and in clear view f the wrkers. If an peratr r ther third party prvides the stand-by persn, it will be the respnsibility f the manager/supervisr in charge t verify that the persn has been, CPR, and First Aid trained, and that they have been prvided the prper respiratry equipment. Only emplyees may wear respiratr equipment. If emplyees will use client r ther third party equipment, the equipment must be inspected t ensure it is safe t use and meets s requirements. Uncntrlled cpy if printed. Valid n day f printing nly. Printed n: 14 December 2016
4 Dc N: Revisin Date: Revisin N. 0 Initial Versin Preparatin: Safety Mgr Authrity: President Issuing Dept: Safety Page: Page 4 f 6 After the equipment has been lcked and tagged ut (per Lckut/Tagut Prgram), pened and the cncentratin has been cleared t less than 10 PPM, the stand-by persn will n lnger be required. Wrk may then be perfrmed withut respiratry equipment, except fr the required 5-minute escape pack. Safe Wrk Prcedures Maintain cmpliance with permit requirements f and any requirements by the client. Verify that prper safety equipment is available, functining prperly and is utilized. Check and remain aware f wind cnditins and directin. Perfrm a thrugh check f the dwnwind area prir t the start f any ptentially hazardus wrk activity. Check fr ther persnnel and ignitin surces. Ventilate wrk areas by venting and purging lines and vessels prir t beginning any wrk activities. Keep all nn-essential persnnel away frm wrk areas. Immediately vacate the area when any mnitr sunds and d nt re-enter withut prper respiratry prtectin. Required Equipment The fllwing equipment shall be prvided and used as required by this prgram: Methds f detecting by the use f fixed r prtable mnitrs and will alarm at the apprpriate permissible expsure limits f 20 PPM fr 1910 r 10 PPM fr 1926? Persnal r area mnitrs that alarm when PEL exceeds the preset level f 20 PPM fr OSHA 1910 r 10 PPM fr OSHA 1926 requirements. Prtable gas testing instrument, either electrnic r manual pump perated, capable f testing the suspected cncentratins f in the system. Each testing instrument must be capable f testing the suspected cncentratins f by using the manufacturer s recmmended calibrated tube r ther means f measuring the cncentratin f gas. Testing instruments shall be calibrated peridically accrding t the manufacturer s recmmendatin, and at least annually. Calibratin kits with regulatr fr calibrating the persnal mnitr. Calibratin gas cylinder fr testing the persnal mnitr. Apprved self-cntained breathing apparatus r airline respiratr with escape SCBA shuld be used with with a 5-minute escape pack, and shall be wrn when pening the equipment t the surrunding atmsphere. At least ne persn (per tw wrkers), equipped with a SCBA will act as a stand-by persn and may nt participate in the wrk being perfrmed until the atmsphere has been tested and fund t have n present in quantities ver 10 PPM. The stand-by persn shall be statined up wind, within 100 feet and in clear view f the wrkers. If an peratr r ther third party prvides the stand-by persn, it will be the respnsibility f the manager/supervisr in charge t verify that the persn has been, CPR, and First Aid trained, and that they have been prvided the prper respiratry equipment. Only emplyees may wear respiratr equipment. Uncntrlled cpy if printed. Valid n day f printing nly. Printed n: 14 December 2016
5 Dc N: Revisin Date: Revisin N. 0 Initial Versin Preparatin: Safety Mgr Authrity: President Issuing Dept: Safety Page: Page 5 f 6 If emplyees will use client r ther third party equipment, the equipment must be inspected t ensure it is safe t use and meets s requirements. Respiratr wearers requiring crrective eyewear will be fitted with spectacle kits accrding t the respiratr manufacturer, at n expense t the emplyee. Respiratrs and their cmpnents, including all fittings f hses, shall nt be interchanged, which if dne, wuld vilate the apprval rating f said respiratr r related equipment. Medical Each emplyee shall have cmpleted a medical evaluatin by a physician r licensed health care prfessinal t determine the emplyee's ability t wear a respiratr as required by the Respiratry Prtectin Prgram. Each emplyee will successfully cmplete the medical questinnaire and examinatin befre being allwed t be fit tested with a respiratr. Training Emplyees required t wrk n lcatins will be trained. Training shall cnsist f: Physical and chemical prperties f Surces f Human physilgy Signs and symptms f expsure, acute and chrnic txicity Symptmatlgy f expsure Medical evaluatin Wrk prcedures Persnal prtective equipment required wrking arund Use f cntingency plans and emergency respnse Burning, flaring, and venting f State and federal regulatry requirement release dispersin mdels Rescue techniques, first aid, and pst expsure evaluatin Use, care, and calibratin f persnal mnitrs and gas detectin instruments Respiratr inspectins and recrd keeping Each respiratr wearer will cmplete Respiratry Prtectin training and a Respiratr Fit Test, after being given a medical clearance and befre entering any lcatin. Emplyees and ther persnnel visiting lcatins wh will nt be invlved in the wrk shall be briefed n the fllwing prir t entering: Site-specific surces f Health hazards f Rutes f egress Emergency assembly areas Uncntrlled cpy if printed. Valid n day f printing nly. Printed n: 14 December 2016
6 Dc N: Revisin Date: Revisin N. 0 Initial Versin Preparatin: Safety Mgr Authrity: President Issuing Dept: Safety Page: Page 6 f 6 Applicable alarm signals and Hw t respnd in the event f an emergency. Rescue Each emplyee, when wrking alne in a designated area, shall plan and becme familiar with self-escape prcedures t include being aware f wind directin and bstacles t avid when exiting the wrk area. Emplyees wrking under the buddy system shall pre-plan an emergency rescue and/r evacuatin prcedure prir t cmmencing wrk, and arrange fr peridic cmmunicatins with his/her supervisr, and dcument the discussin n each emplyee s service reprt. Respiratr Inspectins Respiratrs will be inspected by the emplyee befre each use and at least mnthly. The inspectin will include the respiratr face piece, hse, harness, 5minute escape pack cylinder and all ther cmpnents f the air supply systems used. Mnthly inspectins will be dcumented as per Respiratry Prtectin Prgram, and will be kept n file at the lcal ffice fr review during safety audits. Mnitrs and Gas Detectr Calibratin Each persnal mnitr shall be calibrated at least mnthly and the results recrded n the calibratin lg. Thse mnitrs that d nt require calibrating shall be bump checked with calibratin gas t test alarms, mnthly r prir t use if nt used rutinely. Uncntrlled cpy if printed. Valid n day f printing nly. Printed n: 14 December 2016
HYDROGEN SULFIDE (H2S)
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