ISOPA MDI / TDI BULK DISCHARGE & STORAGE ASSESSMENT Version February 2014

Transcription

1 Versin February 2014 The infrmatin cntained in this ISOPA MDI / TDI Bulk Discharge and Strage Assessment is believed t be accurate. ISOPA disclaims any liability in cnnectin with the use f this infrmatin by its members. It is the respnsibility f the member user t verify the accuracy f this infrmatin. Custmer infrmatin Assessed cmpany: 1 Name 2 Street + number 3 Pstal / Zip cde 4 City 5 Cunty 6 Cuntry 7 Cntact persn 8 Telephne number 9 address 10 Signature Assessment f strage cntaining: Prduct TDI MDI Assessr(s): 11 Name 12 Cmpany 13 Name 14 Cmpany 15 Date f assessment: dd-mm-yyyy 16 Signature

2 General Infrmatin Assessed cmpany lcatin is certified fr: 17 Quality ISO ISO / TS QS-9000 / VDA Envirnment and/r Health & Safety ISO EMAS 22 SCC / VCA 23 OHSAS Assessed cmpany lcatin falls within the scpe f the Seves II (96/82/EC ) r III Directive (2012/18/EU) r a natinal equivalent legislatin? Yes N Unknwn EHS 25 Visibility f EHS infrmatin Site shws clearly visible infrmatin abut EHS subjects Sme infrmatin visible at ffices N infrmatin visible Safety Data Sheet 26 Availability f latest versin f SDS frm supplying cmpany Yes N Cmments:

3 General Infrmatin Lcatin 27 Access rad t custmer lcatin Straight / tw lanes Narrw / tw lanes 28 Custmer lcatin Lcatin is signpsted and easy t find Lcatin easy t find 29 Lcatin f strage and prductin Industrial area Rural area Ppulated area facility Makes sharp bend and is narrw Lcatin difficult t find Husekeeping 30 Signs f previus spillage at N signs Sme sign f spillage visible Several spillages visible discharge lcatin 31 Signs f previus spillage at strage N signs Sme sign f spillage visible Several spillages visible lcatin 32 Husekeeping at entry f site Clean and tidy Untidy Dirty 33 Husekeeping discharge area Clean and tidy Untidy Dirty 34 Husekeeping strage lcatin Clean and tidy Untidy Dirty Cmments:

4 Prtectin and Hygiene Persnal Prtective Equipment 35 Available Gggles / Safety glasses 36 Safety helmet 37 Overall 38 Suitable impervius glves 39 Safety shes / bts 40 Used Gggles / Safety glasses 41 Safety helmet 42 Overall 43 Suitable impervius glves 44 Safety shes / bts 45 Respiratry equipment/ face mask with apprpriate filter fr rutine use 46 System in place t manage filter Yes lifetime Available and clse t discharge pint / strage tank Available n site Nt available N Cmments:

5 Prtectin and Hygiene Persnal hygiene Segregatin f areas 47 Clth changing / washing area Segregated 48 Eating / drinking area Segregated 49 Smking area Segregated Industrial hygiene 50 Peridic mnitring f vapurs Frequent mnitring Incidental mnitring 51 Badges (TDI detectin) Available and frequently used Available but nly used in case f emergency Nt segregated Nt segregated Nt segregated N mnitring N badges available r used Cmments:

6 Receptin and Dcumentatin Receptin 52 Lcatin f receptin At the gate At the discharge lcatin 53 Infrmatin abut lcal prcedures Clearly indicated and / r explained Instructins given but nt clear and instructins 54 Checking dcuments Delivery dcuments are checked at the gate and at discharge lcatin Delivery dcuments are checked at discharge lcatin 55 Identity check f driver Always checked Checked n ad-hc basis 56 ISOPA driver certificates ISOPA driver certificates are rutinely checked ISOPA driver certificates are checked n ad-hc basis At the plant N infrmatin given N checks n dcuments are made Nt checked ISOPA driver certificates are nt checked Free space in strage tank 57 Check delivery vlume against free strage space Checks are always dne Checks are dne in case f dubt N checks are dne Crss cntaminatin 58 Prduct identity check Checks are dne n paper versus equipment Checks are nly dne n paper Site traffic 59 Ruting n site Ruting instructins given Limited ruting signs available Sampling 60 Sample taking Samples are nt taken Samples are taken by the peratr 61 Sampling lcatin Samples are taken frm hse Samples are taken frm dedicated sampling pint f the custmer N checks are dne N ruting instructins given Samples are taken by the driver Samples are taken frm tanker Cmments:

7 Incident management Prduct knwledge 62 Cvering and educating n prduct specific risks and ptential hazards Regular training f staff, particulary in case f new emplyment r new prducts Occasinal training N specific training Emergency instructins 63 Instructin fr spillage 64 Instructins fr fire and ther emergencies Emergency stp 65 Emergency stp fr discharge Clear instructins in the case f spillage available Sme inf is available Clear instructins available Sme inf is available Emergency stp fr discharge is autmatic incl. valve / pushing buttn Emergency stp via clsing valve / pushing buttn 66 Access t emergency stp Easy, unrestricted Difficult 67 Distance t emergency stp frm Frm 5-15 m vehicle N instructins available N instructins available N emergency stps available Emergency stp nt accessible Less than 5 r mre than 15 m Emergency exits 68 Emergency exits available 2 r mre emergency exits exist in all areas Only ne emergency exit exists 69 Emergency exits clearly marked Yes and well lit Yes N N emergency exit available Emergency alarms 70 Fire alarm Present and peridically tested Nt present Cmments:

8 Incident management Emergency tls 71 Fire extinguishers At least tw fire extinguishers are present Only ne fire extinguisher present 72 Spillage absrbant Mre than 200 litres f suitable absrbent Less than 200 litres f suitable absrbent 73 Spillage decntaminant present Mre than 200 litres f suitable decntaminant present present Less than 200 litres f suitable decntaminant present 74 Self-cntained breathing apparatus Yes, available n site, peple trained in use N fire extinguishers present N suitable absrbent available N suitable decntaminant present Nt available Emergency rganisatin 75 Emergency respnse rganisatin 76 Reprting f incidents 77 Prfessinal medical service available Organisatin present ER exercises at least nce a year fr iscyanates Reprting f incidents dne n a frmal basis Organisatin present ER exercise nce a year N regular reprting dne Yes, n site Lcal, respnse time < 10 minutes N Organisatin nt present N evidence f ER exercise N reprting dne Cmments:

9 Incident management Emergency shwers / eye wash facility 78 Emergency shwer available Yes N 79 Eye wash facility available Yes N 80 Distance safety shwer(s) frm pint f discharge Less than 10 m Between 10 and 20 m 81 Frst prtectin Safety shwer is frst prtected Temperature f water des nt give a risk t health 82 Maintenance f safety shwer Signs f regular maintenance are visible 83 Quality f eye wash facility Well maintained eye wash facility 84 Safety shwer and eye wash facility tested fr 'Leginella' 85 Distance f eye wash frm pint f discharge Cmments: Yes Sme prtectin is dne N real evidence f frst prtectin Sme maintenance is dne Dubt abut perfrmance f safety shwer Eye wash facility shws signs f pr maintenance Less than 10 m Between 10 and 20 m Mre than 20 m and / r nly accessible via several bstacles N frst prtectin N sign f any maintenance Clear signs f bad maintenance n eye wash facility N Mre than 20 m and / r nly accessible via several bstacles

10 Discharge area General 86 Discharge area under cver Rf is present Discharge area is well prtected Sme prtectin is present 87 Quality f surface discharge area Liquid tight Slightly permeable Permeable N cver r prtectin/ Height t less Rain water drainage 88 Rain water drainage Clsed sewer Open sewer Cllectin f spilled prduct 89 Draining directin f spillage Away frm vehicle Partially away frm vehicle 90 Cntainment f spillage Vehicle Cntainment nt cnnected with sewer system Cntainment with clsed valve / drain t sewer system 91 Psitin f bulk vehicle Hrizntal Slight inclinatin 92 Vehicle mvement prtectin Wheel chcks Key / brake prtectin 93 Vehicle access / exit N restrictins Alarm when mvement ccurs Access rad has width f at least ne vehicle Reversing necessary N drainage Arund vehicle N cntainment Very steep inclinatin N prtectin N access rad Cmments:

11 Discharge area Instructins / management 94 Availability discharge instructins Available, displayed and trained Available but nt displayed 95 Unlading peratin is dne Yes, always used Available but nt regulary used accrding t a written check list 96 Type f discharge instructins Using pictures/ icns/ transperant and be displayed at discharge lcatin using text in several languages and be displayed at discharge lcatin 97 Surrunding traffic management Surrunding traffic is guided Sme restrictin r guidance t lcal traffic Nt available N checklist avaiable nly lcal language and nt displayed at discharge lcatin N management f surrunding traffic Cmments:

12 Discharge installatin Generally 98 Separated unlading fr diiscyanates and ther chemicals 99 Custmer is prepared fr tp discharging Yes Yes N N Labelling 100 Discharge cnnectins All cnnectins are clearly labelled and visible Sme labelling is present but nt very clear N labelling is present Cnnectrs 101 Cupling DN50 flange (recmmended standard) DN80 flange Other cuplings 102 Cnnectin piece(s) N cnnectin pieces are used One cnnectin piece is used Mre than ne cnnectin piece(s) is used 103 Risk f mixing with ther prduct(s) N Yes Cmments:

13 Discharge installatin Discharge methd 104 Type f discharge Pump Nitrgen r dry air 105 Vapur return line Is present, f gd quality and is rutinely Is present but size and/r quality is 106 Vapur flw rate mnitring used Is present and stps discharging in case f n indicatin f flw suspect Is present and and manually mnitred Cmpressed air frm truck N vapur return line present N vapur flw rate mnitring present Discharge platfrm 107 Cnstructin Discharge platfrm with stairs and fall prtectin 108 Access t tp f bulk equipment Safe access withut restrictins 109 Safety n platfrm fall prtectin If n platfrm available, is safety harness and safe cnnectin pints available Discharge hse 110 Way f discharge Unlading arm Flexible hse 111 Hse lifting Lifting device perated by ne persn 112 Hse length Hse length is functinal fr discharge applicatin Discharge platfrm withut fall prtectin Narrw access / access via bulk equipment Lifting device t be perated by tw persns Slightly shrt / lng hse resulting in unnecessary bending r maneuvring with vehicle N platfrm available/ dubts abut fall prtectin N access prvided N platfrm available and n safety harness and cnnectin pints available N lifting device present Hse length abve 10 m r t shrt t allw safe cnnectin Cmments:

14 Discharge installatin Discharge hse 113 Hse size 2 inch 114 Hse wnership 115 Hse quality (inside & utside) 116 Hse capping Dedicated t prduct Custmer wned Gd, bth inside and utside/ hse material fits t prduct Hse capped with blind flange n bth sides 2 inch but cnstructed unnecessary heavy Dedicated t prduct Nt custmer wned Sme signs f inside fuling, dubts abut hse material Hse capping insufficiently 117 Hse strage Hse stred inside under dry cnditins Hse stred under cver 118 Hse inspectin (visual) Vapur return hse Hse shws signs f regular inspectin (tagging) Hses are inspected but evidence is nt directly visible 119 Hse size 2 inch Between 1 and 2 inch Mre r less than 2 inch Nn-dedicated t prduct Haulier r supplier wned Fuled and / r damaged / unsuitable hse material Hse nt capped Hse stred in pen air N hse inspectin takes place Lwer r equal than 1 inch Lighting 120 Lighting at discharge lcatin Gd Gd lighting in mst places but sme areas t dark Insufficient Cperatin driver/peratr 121 Cperatin during cnnectins / discnnectins Yes 122 Presence during discharge Yes, bth Yes, the peratr Cmments: N Only the driver r nbdy present

15 Strage tank Size 123 Strage tank size Mre than ne truck lad Cntainment 124 Bunding Bund is present and capable t stre largest tank vlume. Bund has n cracks. Diiscyanates and ther chemicals in separate bund Bund is present but dubts abut bund cntent. Bund has cracks. Diiscyanates and ther chemicals tanks in ne bund 125 Draining f bunded area Draining f bund via installed pump Draining via (nrmally clsed) valve Less than ne truck lad N bunding present N cntainment Equipment 126 Quality f tank New r well maintained 127 Quality f lines New r well maintained 128 Quality f instrumentatin New r well maintained Sme signs f lack f maintenance f lder equipment Sme signs f lack f maintenance f lder equipment Sme signs f lack f maintenance f lder equipment Pr quality with lack f maintenance Pr quality with lack f maintenance Pr quality with lack f maintenance Temperature 129 Measurement 130 Temperature cntrl Temperature measurement inside tank Clear readability Temperature measurement inside tank with autmatic cntrl External measurement Manual cntrl f temperature r tank placed in heated strage rm 131 Heat transfer medium Suitable electrical tracing r il heating water with safety heat exchanger N measurement N temperature cntrl water with standard heat exchanger Cmments:

16 Strage tank Circulatin / mixing 132 Circulatin Circulatin by pump Circulatin by mixing unit Pressure 133 Measurement Pressure indicatin Visible frm discharge lcatin Pressure indicatin Only visible after climbing t tp f strage tank 134 Cntrl Over and under pressure cntrl 135 Prtectin Safety equipment fr under and verpressure is installed and well maintained Only under r verpressure prtectin is installed 136 Alarm Present Vapur quality 137 Inlet gas quality Nitrgen / air with demnstrated quality Dubt abut quality f inlet gas N mixing pssible N pressure indicatin available N cntrl N prtectin installed Nt present Inlet f ambient air Building 138 Ventilatin f strage building Gd ventilatin f building Sme ventilatin exists but effect dubted 139 Lighting Gd Gd lighting in mst places but sme areas t dark N ventilatin present Insufficient Piping 140 Labelling All pipes prperly labelled with prduct name and flw directin Sme pipes labelled 141 Cnditin In gd cnditin Signs f rust 142 Insulatin In gd cnditin Insulatin shws sme damage Parts are nt fully insulated N labelling In bad cnditin Dubt exists abut integrity f piping Insulatin nt present Cmments:

17 Strage tank Pump 143 Pump Pump in gd cnditin Dubt exists abut perfrmance f pump Filtratin 144 Filter Sufficient size filter present and f gd quality Small filter installed 145 Filter(s) cleaned / changed frequently Yes N Pump is ut f peratin r is likely nt functining N filter present Level 146 Indicatin Reliable level indicatin Dubt abut reliability f level indicatin 147 Side glass level indicatin Nt present Prtected side glass present 148 High level alarm High level alarm via level instrument High level alarm via level instrument and independent level switch 149 High level alarm functin High level stps the discharge Acustical r ptical alarm 150 Visibility f level indicatin Visible frm discharge lcatin Visible frm cntrl rm Level indicatin nly visible clse t strage tank N level indicatin Unprtected side glass present N high level alarm N functin Level indicatin nly visible after climbing n strage tank Venting f strage 151 Directin 152 Avidance f crss cntaminatin Strage vents t safe lcatin utside strage area Venting via separate lines N cnnectin with ther strage tanks Strage vents t area where ccasinally persnnel is present Venting in cmbinatin with ventilatin f building 153 Vapur treatment Present Strage vents inside strage building r t lcatin where persnnel is wrking Venting line in cmbinatin with venting f ther strages Nt present Cmments:

18 Risk Management & Management f Change Risk analysis 154 Risk analysis f installatin Yes, specify methd used... Internal prcedure N special risk analysis 155 Dne by Expert team r specilaist staff Staff 156 Dcumentated Yes N 157 Last update dd/mm/yyyy Management f Change 158 Risk analysis prir t changes Yes, specify methd used... Internal prcedure N 159 Written prcedures fr changes Yes N 160 Respnsibilty fr written prcedures & changes Expert team Specialist staff Other. Repair & maintenance 162 Regular check f safety equipment Yes, implementatin f regular checks, accrding results f risk analysis 163 Qualified maintenance prviders Use f prfessinal, qualified prvidersr specialist staff with prduct-knwledge and experience 164 Permit prcedures fr hazardus wrk used Cmments: Always Occasinal checks Rarely N checks Staff r prvider withut special experience Permit prcedures nt used